This work is a study of hydrogen generation of Al-NaCl powders in different reaction mediums. Water, KOH and NaOH were used as reaction mediums for the comparison of the hydrogen generation rate. The effects of the milling time, NaCl wt%, reaction temperature and reaction mediums were investigated. Al was milled with NaCl in order to increase the hydrogen generation rate. Increasing NaCl wt% and reaction temperature also increased the hydrogen generation rate. Al reactivity can be enhanced by increasing milling time, NaCl wt%, reaction temperature and by using alkaline solutions.
ALEKSANDROV, Y. A., TSYGANOVA, E. I., PISAREV, A. L., 2003. Reaction of aluminum with dilute aqueous NaOH solutions, Russ. J. Gen. Chem., 73 (5), 689694. https://doi.org/10.1023/A:1026114331597
BUNKER, C. E., SMITH, M. J., 2011. Nanoparticles for hydrogen generation, Journal Materials Chemical, 21, 12173–12180. https://doi.org/10.1039/C1JM10856E
CZECH, E., TROCZYNSKI, T., 2010. Hydrogen generation through massive corrosion of deformed aluminum in water, International Journal of Hydrogen Energy , 35, 1029-1037. https://doi.org/10.1016/j.ijhydene.2009.11.085
DUPIANO, P., STAMATIS, D., DREIZIN, E. L., 2011. Hydrogen production by reacting water with mechanically milled composite aluminum-metal oxide powders, International Journal of Hydrogen Energy , 36(8), 4781-4791. https://doi.org/10.1016/j.ijhydene.2011.01.062
HO, C.-Y., 2017, Hydrolytic reaction of waste aluminum foils for high efficiency of hydrogen generation, International Journal of Hydrogen Energy, 42 (31), 19622-19628. https://doi.org/10.1016/j.ijhydene.2017.06.104
JIAA Y., SHENA J., MENGA H., DONGA Y., CHAIA Y., WANG N., 2014. Hydrogen generation using a ball-milled Al/Ni/NaCl mixture, Journal of Alloys and Compounds, 588, 259–264. https://doi.org/10.1016/j.jallcom.2013.11.058
MCARTHUR, H., SPALDİNG, D., 2004, Engineering Materials Science: Properties, Uses, Degradation, Remediation, Elsevier, UK, 1st Edition, Paperback ISBN:9781898563112, eBook ISBN:9781782420491, Imprint: Woodhead Publishing, UK, page count: 608.
LIU S., FAN M.-q., WANG C., HUANG Y.-X., CHEN D., BAI L.-Q., SHU K.-Y., 2012. Hydrogen generation by hydrolysis of Al-Li-Bi-NaCl mixture with pure water, International Journal Hydrogen Energy, 37, 1014-1020. https://doi.org/10.1016/j.ijhydene.2011.03.029
LIU, Y., GE, H., WANG, X., LIU, H., DONG, Z., LI, S., YAN, M., 2015. Study on hydrogen generation from the hydrolysis of a ball milled aluminum/calcium hydride composite, RSC Advances, 5, 60460-60466. https://doi.org/10.1039/C5RA09200K
NIE, H., SCHOENITZ, M., DREIZIN E. L., 2012. Calorimetric investigation of the aluminum water reaction, International Journal of Hydrogen Energy, 37 (15), 11035–11045. https://doi.org/10.1016/j.ijhydene.2012.05.012
PORCIÚNCULA, C. B., MARCILIO, N. R., TESSARO, I. C., GERCHMANN, M., 2012. Production of hydrogen in the reaction between aluminum and water in the presence of NaOH and KOH, Brazilian Journal of Chemical Engineering, 29(2), 337-348. https://doi.org/10.1590/S0104-66322012000200014
PYUN, S., MOON, S., 2000. Corrosion mechanism of pure aluminium in aqueous alkaline solution, J Solid State Electrochem, 4, 267–272. https://doi.org/10.1007/s100080050203
RAZAVI-TOUSI, S.S., SZPUNAR, J.A., 2016. Effect of addition of water-soluble salts on the hydrogen generation of aluminum in reaction with hot water, Journal of Alloys and Compounds, 679, 364-374. https://doi.org/10.1016/j.jallcom.2016.04.038
RONG, S., BAOZHONG, Z., YUNLAN, S., 2017. The effect of NiCl2 and Na2CO3 on hydrogen production by Al/H2O system, International Journal of Hydrogen Energy, 42, 3586-3592. https://doi.org/10.1016/j.ijhydene.2016.07.254
ROSENBAND, V., GANY, A., 2010. Application of activated aluminum powder for generation of hydrogen from water, International Journal Hydrogen Energy, 35, 10898-10904. https://doi.org/10.1016/j.ijhydene.2010.07.019
WIKIPEDIA CONTRIBUTORS. (2020, June 2). Hydrogen production. In Wikipedia, The Free Encyclopedia. Retrieved 13:21, June 26, 2020, from https://en.wikipedia.org/w/index.php?title=Hydrogen_production&oldid=960349940
YANG, B. C., CHAI, Y. J., YANG, F. L., ZHANG, Q., LIU, H., WANG, N., 2018. Hydrogen generation by aluminum‐water reaction in acidic and alkaline media and its reaction Dynamics, International Journal of Energy Research, 42, 1594-1602. https://doi.org/10.1002/er.3953
YOLCULAR, S., KARAOGLU, S., 2017. Activation of Al powder with NaCl assisted milling for hydrogen generation, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 39(18), 1919-1927. https://doi.org/10.1080/15567036.2017.1390009
ZHUK, A. Z., SHEINDLIN, B. V., KLEYMOV, V., SHKOLNIKOV, E. I., LOPATIN, M. Y., 2006. Use of low cost Aluminum in electric energy production, J. Power Sources, 157, 921-926. https://doi.org/10.1016/j.jpowsour.2005.11.097
This work is licensed under a Creative Commons Attribution-NoDerivatives 4.0 International License.
Copyright (c) 2020 Rating Academy Ar-Ge Yazılım Yayıncılık Eğitim Danışmanlık ve Organizasyon Ticaret Ltd. Şti